Iron(II) complexes featuring chiral PNNP diferrocene: Synthesis and characterization of potential hydrogenation catalysts
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- 作者：Afrooz Zirakzadeha ; afrooz.zirakzadeh@tuwien.ac.at" class="auth_mail" title="E-mail the corresponding author ; Sara R.M.M. de Aguiara ; Michael Widhalmb ; Kurt Mereiterc ; Karl Kirchnera
- 关键词：Ferrocenes ; Chiral ligands ; Iron complexes
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 September 2016
- 年：2016
- 卷：819
- 期：Complete
- 页码：260-265
- 全文大小：733 K
文摘
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Chiral PNNP biferrocene with either imine or amine nitrogen coordination sites were synthesized.
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Only the imine-type formed dicationic iron complexes.
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Complexes were active in hydrogenation and transfer hydrogenation reactions.