About the nanostructure of the ternary system water - [BMIm]PF6 - TX-100
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- 作者：Harun Bilgili ; Matthias Bü ; rger ; Cosima Stubenrauch ; cosima.stubenrauch@ipc.uni-stuttgart.de" class="auth_mail" title="E-mail the corresponding author ; Jan H. Porada
- 关键词：Nanostructure of water &ndash ; [BMIm]PF6 &ndash ; TX-100 ; Microemulsifying IL in water ; Hydrophobic ionic liquids
- 刊名：Journal of Colloid and Interface Science
- 出版年：2016
- 出版时间：15 December 2016
- 年：2016
- 卷：484
- 期：Complete
- 页码：237-248
- 全文大小：2880 K
文摘
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The system H2O – [BMIm]PF6 – TX-100 was investigated by means of PFG NMR and ROESY NMR.
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An alternative model for the nano structure of H2O – [BMIm]PF6 – TX-100 is suggested.
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TX-100 is not adsorbed at the interface between water and IL but forms normal micelles.
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Both water and IL are in the same domain.
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TX-100 acts not as a surfactant but as a dissociation enhancer for the IL.