Synthesis, crystal structure and electronic properties of [3.3]metaparacyclophane-bridged bimetallic ruthenium alkynyl complexes
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- 作者：Xiaoxiao Wang ; Xiaoxiao You ; Zhen-Peng Shang ; Jianlong Xia ; jlxia@whut.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Bimetallic complexes ; Ruthenium ; [3 ; 3]metaparacyclophanes ; Crystal structure ; Synthesis ; Electronic properties
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 February 2016
- 年：2016
- 卷：803
- 期：Complete
- 页码：111-118
- 全文大小：1218 K
文摘
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[3,3]Metaparacyclophanes have been used as bridge ligands.
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Single crystal X-ray structures are obtained for all of the complexes.
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Substituent effect of intramolecular edge-to-face interactions has been studied.
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–CN, –NO2 substituents can enhance the stabilities of mono oxidized species.