Modified synthesis of mixed-ligand dinuclear Ru-Ir, Ru-Rh, and Ru-Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5tBu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6
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- 作者：Ryuichi Shimogawaa ; Toshiro Takaoa ; b ; takao.t.aa@m.titech.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Hiroharu Suzukia
- 关键词：Ruthenium ; Rhodium ; Iridium ; Hydride ; Hetero-bimetallic cluster
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 September 2016
- 年：2016
- 卷：818
- 期：Complete
- 页码：168-178
- 全文大小：1217 K
文摘
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Hetero-bimetallic trihydride complexes were efficiently synthesized.
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Polyhydride clusters containing C5(tBu)3H2 and arene ligands were synthesized.
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The hydrides were simply introduced with 2-propanol in the presence of a base.
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The hetero-bimetallic chloride complexes were used as a starting material.