Synthesis of an amidosulfonate-tagged biphenyl phosphine and its application in the Suzuki-Miyaura reaction affording biphenyl-substituted amino acids in water
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- 作者：Ji艡í ; Schulz ; Ivana Cí ; sa艡ová ; Petr &Scaron ; t臎pni膷ka ; stepnic@natur.cuni.cz" class="auth_mail" title="E-mail the corresponding author
- 关键词：Biphenyl phosphines ; Phosphinoamides ; Sulfonates ; Palladium ; Suzuki&ndash ; Miyaura cross-coupling ; Amino acids
- 刊名：Journal of Organometallic Chemistry
- 出版年：2015
- 出版时间：1 November 2015
- 年：2015
- 卷：796
- 期：Complete
- 页码：65-72
- 全文大小：615 K
文摘
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A new polar phosphino-biphenyl ligand was synthesized.
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The sulfonatomethyl amide moiety enhances its affinity to water.
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The ligand forms active Pd catalysts for Suzuki–Miyaura reaction.
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The cross-coupling can be performed in water to give biphenyl-substituted amino acids.