The range in static stereochemistry of the cation distortion isomers of the [Cu (chelate)2Cl]+ cation, where chelate=bipy, phen or bipyam. The low temperature crystal structure (150 K) of [Cu (bipy)2C

详细信息    查看全文

• 作者：Brophy ; Mark ; Murphy ; Gillian ; Osullivan ; Cathal ; Hathaway ; Brian ; Murphy ; Brian
• 关键词：Low temperature ; Static copper(II) stereochemistries ; Cation distortion isomer
• 刊名：Polyhedron
• 出版年：1999
• 出版时间：January 8, 1999
• 年：1999
• 卷：18
• 期：5
• 页码：611-615
• 全文大小：260 K

文摘

Low temperature crystallography (150 K) has been used to confirm that the two extreme [Cu (chelate)₂Cl] [Y] stereochemistries of 3 [Cu (bipy)₂Cl] [PF₆]·H₂O, trigonal bipyramidal and 6 [Cu (phen)₂Cl] [BPh₄], trigonal bipyramidal distorted square based pyramidal, are genuine and static stereochemistries of the copper (II) ion.