Transition metal chemistry of large-bite bisphosphines, N,N-bis(diphenylphosphinobenzyl)-N-phenylamine and bis(2-diphenylphosphinobenzyl)ether
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10">Large bite bisphosphines containing N and O atoms in the ligand framework have been synthesized.

15">Cis and trans complexes of Pd(II) and Pt(II) have been isolated.

Chelating as well as bridging coordination modes have been observed.

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