Hydroesterification of methyl 10-undecenoate in thermomorphic multicomponent solvent systems—Process development for the synthesis of sustainable polymer precursors
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- 作者：Tom Gaide ; Arno Behr ; Alexander Arns ; Francesco Benski ; Andreas J. Vorholt ; Andreas.vorholt@bci.tu-dortmund.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：[Pd2(dba)3] ; tris(dibenzylideneacetone)dipalladium ; 1 ; 2-DTBPMB ; 1 ; 2-bis((di-tert-butylphosphino)methyl)benzene ; CDT ; 1 ; 5 ; 9-cyclododecatriene ; DPEphos ; (oxybis(2 ; 1-phenylene))bis(diphenylphosphine) ; DPPB ; 1 ; 4-bis(diphenylphosphino)butane ; DPPE ; 1 ; 2-bis(diphenylphosphino) ethane ; DPPH ; 1 ; 6-bis(diphenylphosphino)hexane ; ICP-OES ; inductive coupled plasma optical emission spectrometry ; MSA ; methanesulfonic acid ; NiXANTphos ; 4 ; 6-bis(diphenylphosphino)-10H-phenoxazine ; Pd(acac)2 ; palladiumacetylactonat
- 刊名：Chemical Engineering & Processing
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：99
- 期：Complete
- 页码：197-204
- 全文大小：538 K
文摘
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Highly selective hydroesterification of renewable methyl 10-undecenoate.
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10">Synthesis of polymer building blocks.
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15">Separation of product and catalyst via thermomorphic multicomponent solvent systems.
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Catalyst recycling.