The new Zintl phases Eu21Cd4Sb18 and Eu21Mn4Sb18
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- 作者：Yi Wang ; Gregory M. Darone ; Svilen Bobev ; bobev@udel.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Crystal structure ; Single-crystal X-ray diffraction ; Europium ; Antimony ; Zintl phases
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：238
- 期：Complete
- 页码：303-310
- 全文大小：3038 K
文摘
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Eu21Mn4Sb18 and Eu21Cd4Sb18 are novel compounds in the respective ternary phase diagrams.
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For both structures, the Zintl-Klemm rules are followed, and both are small gap semiconductors.
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Eu21Mn4Sb18 and Eu21Cd4Sb18 are air-stable Zintl phases and could be new thermoelectric materials.