The effect of high intensity ultrasound on the loading of Au nanoparticles into titanium dioxide

详细信息    查看全文

• 作者：Valentina Belova ; Tatiana Borodina ; Helmuth Mö ; hwald ; Dmitry G. Shchukin
• 关键词：Cavitation ; Nanocomposite ; Mesoporous materials ; Titanium dioxide ; Photocatalyst
• 刊名：Ultrasonics Sonochemistry
• 出版年：2011
• 出版时间：January 2011
• 年：2011
• 卷：18
• 期：1
• 页码：310-317
• 全文大小：1474 K

文摘

Novel metal/semiconductor nanocomposites have been synthesized from pre-formed components by applying high intensity ultrasound irradiation. Positively and negatively charged Au nanoparticles were intercalated into mesoporous TiO₂ by sonication. The synthesized nanocomposites with implanted gold nanoparticles possess a narrow pore-size distribution around 7 nm and a large surface area of about 210 m²/g. The intercalation of the Au nanoparticles into the TiO₂ framework depends on the charge of the Au nanoparticles, time and amplitude of ultrasonic treatment. The experiments show that at 20 min of ultrasonic irradiation the volume fraction of the negatively charged Au nanoparticles intercalated into TiO₂ is 15 % . By contrast, at the same time, 8.1 % of positively charged Au nanoparticles with a diameter of about 6–7 nm enters into the TiO₂ matrix.

The characterization of the samples was carried out by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, scanning electron microscopy, Fourier transform infrared measurements and BET analysis. The structure of TiO₂ was not considerably affected by the intercalation of the Au nanoparticles. TiO₂ doped with negatively charged Au nanoparticles presented a higher photocatalytic activity (75 wt. % ) than TiO₂ loaded with positively charged Au nanoparticles (62 wt. % ), because of an enlarged surface area and quantity of Au nanoparticles in titania.