Superhalogens as building blocks of complex hydrides for hydrogen storage
详细信息 查看全文
- 作者：Ambrish Kumar Srivastava ; Neeraj Misra ; mishra_neeraj@lkouniv.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Superhalogen ; Borohydrides ; Lithium complexes ; Hydrogen storage ; Density functional theory
- 刊名：Electrochemistry Communications
- 出版年：2016
- 出版时间：July 2016
- 年：2016
- 卷：68
- 期：Complete
- 页码：99-103
- 全文大小：844 K
文摘
- •
BH4−, complex anion in LiBH4, is a ‘superhalogen’.
- •
New complex anions, BH4 − x(BH4)x− (x = 1–4) have been designed.
- •
The hydrogen storage properties of LiBH4 − x(BH4)x− complexes are discussed.
- •
The dehydrogenation energy of complexes depends on the nature their anions.