Borohydride-induced destabilization of hydrazine borane
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- 作者：F. Tochea ; R. Chiriaca ; U.B. Demircib ; umit.demirci@um2.fr" class="auth_mail ; P. Mieleb
- 关键词：Ammonia borane ; Hydrazine borane ; Lithium borohydride ; Sodium borohydride ; Thermolysis
- 刊名：International Journal of Hydrogen Energy
- 出版年：5 June 2014
- 年：2014
- 卷：39
- 期：17
- 页码：9321-9329
- 全文大小：833 K
文摘
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LiBH4 acts as sacrificial chemical additive and destabilization agent for N2H4BH3.
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LiBH4 in the presence of N2H4BH3 dehydrogenate in milder conditions than neat LiBH4.
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Polyborazylene forms after the release of 12.1 mol H2 from N2H4BH3–LiBH4 (4:1).
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Ceramization of N2H4BH3 into BN starts at temperatures much lower than 500 °C.