Synthesis of bottlebrush copolymers based on poly(dimethylsiloxane) for surface active additives
详细信息 查看全文
- 作者：Stacy L. Peseka ; b ; Yen-Hao Lina ; Hui Zhen Mahc ; e ; Will Kaspera ; Bo Chend ; Brian J. Rohdec ; Megan L. Robertsonc ; Gila E. Steinc ; e ; gestein@uh.edu" class="auth_mail" title="E-mail the corresponding author ; Rafael Verduzcoa ; b ; f ; rafaelv@rice.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Bottlebrush ; Polymer ; PDMS ; PLA ; Surface coatings ; Blends ; Thin films ; XPS ; Contact angle ; Grafting-through
- 刊名：Polymer
- 出版年：2016
- 出版时间：19 August 2016
- 年：2016
- 卷：98
- 期：Complete
- 页码：495-504
- 全文大小：1783 K
文摘
- •
We prepare bottlebrush polymers with multiple side-chain functionalities.
- •
Functional bottlebrush additives accumulate at film interfaces.
- •
Small amounts of additive produce large changes in surface wettability.
- •
Bottlebrushes segregate rapidly during casting.
- •
Surface-active bottlebrushes represent a versatile approach to tailor thin films.