Main pathways in the photochemical transformation of 3-(4-bromophenyl)-1-methoxy-1-methylurea (metobromuron) in aqueous solution
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- 作者：Boulkamh ; Abdelaziz ; Sehili ; Tahar ; Boule ; Pierre
- 关键词：Metobromuron ; Halogenophenylurea ; Phototransformation ; Carbene ; Demethoxylation ; Benzoquinone mono-imine
- 刊名：Journal of Photochemistry and Photobiology A: Chemistry
- 出版年：2001
- 出版时间：October 10, 2001
- 年：2001
- 卷：143
- 期：2-3
- 页码：191-199
- 全文大小：185 K
文摘
Metobromuron (MB) in aqueous solution has a complex photochemical behaviour due to the involvement of two main different routes: demethoxylation of urea moiety and reactions (hydroxylation, oxidation, formation of adducts) resulting from the initial formation of a carbene. Both pathways occur in approximately equal proportions in the case of MB. Comparison with other halogenophenylureas indicates that the position of the halogen atom on the ring and the nature of the substituent on the urea moiety play an important role in the relative importance of these two pathways: the carbene pathway is related to the presence of a halogen atom in para-position on the ring and N-demethoxylation is much easier than N-demethylation. Hydroxylation of the ring without debromination was also observed. The photocatalytic degradation also leads to the formation of several products resulting from hydroxylation of the ring and demethoxylation.