Ouzo effect—New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres

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• 作者：Marija Prekajski^a ; ^{prekajski@vinca.rs" class="auth_mail" title="E-mail the corresponding author} ; ^{prekajski2@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; Miljana Mirković^a ; Bratislav Todorović^b ; Aleksandar Matković^c ; Milena Marinović-Cincović^a ; Jelena Luković^a ; Branko Matović^a
• 关键词：Nanoparticles ; Synthesis ; Thermogravimetric analysis (TGA) ; Infrared spectroscopy ; X-ray diffraction
• 刊名：Journal of the European Ceramic Society
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：36
• 期：5
• 页码：1293-1298
• 全文大小：1364 K

文摘

Nanoemulsion technique was applied for synthesis of carbonated strontium hydroxyapatite (CSrHAp) at room temperature. X-ray powder diffraction analysis accompanied with Rietveld refinement reviled that synthesized powder were single-phase hydroxyapatite. Fourier transform infrared (FTIR) spectroscopy showed that the CSrHAp was A-type substitution. The carbonate amount substituting the hydroxide group in the synthesized apatite was estimated, from the corresponding CO₂ weight loss in the range 600–1100 °C. According to this empirical formula of as synthesized CHAp is Sr₁₀(PO₄)₆(OH)_0.60(CO₃)_0.70. These results were confirmed by the Rietveld refinement analysis. Using scanning electron microscopy analysis it was found that the synthesized CSrHAp particles were spherical in shape and that their sizes were in the nanometer range. Nanoemulsion strategy procedure provides a simple pathway to obtain single-phase CSrHAp.