Binuclear cyano-bridged complex derived from [MnIII(salpn)] and [FeIII(CN)6]: Synthesis, structure and magnetic properties
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- 作者：Vyacheslav A. Kopotkov ; slavaoven@mail.ru" class="auth_mail" title="E-mail the corresponding author ; Denis V. Korchagin ; Artem D. Talantsev ; Roman B. Morgunov ; Eduard B. Yagubskii ; yagubski@icp.ac.ru" class="auth_mail" title="E-mail the corresponding author
- 关键词：Magnetic properties ; Manganese(III) ; Hexacyanoferrate(III) ; Cyano-bridged ; Single-molecule magnets
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：64
- 期：Complete
- 页码：27-30
- 全文大小：676 K
文摘
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A novel binuclear complex [NH3(CH2)3NH3] {[Mn(salpn)(H2O)][Fe(CN)6]} was prepared, structurally and magnetically characterized.
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[MnIII(salpn)(H2O)] and [FeIII(CN)6] moieties are linked between each other via one bridge cyano group.
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Complex exhibits slow magnetic relaxation, suggesting SMM type behavior.