Metal-surfactant interaction as a tool to control the catalytic selectivity of Pd catalysts

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• 作者：A.M. Perez-Coronado^a ; L. Calvo^a ; ^{luisa.calvo@uam.es} ; J.A. Baeza^a ; J. Palomar^a ; L. Lefferts^b ; J.J. Rodriguez^a ; M.A. Gilarranz^a
• 关键词：Palladium ; Nanoparticles ; Catalysis ; AOT ; Nitrite
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：5 January 2017
• 年：2017
• 卷：529
• 期：Complete
• 页码：32-39
• 全文大小：1194 K
• 卷排序：529

文摘

Unexpected lower activity and TOF for small Pd NPs synthetized using water/AOT/isooctane system. Preferential blockage of active sites by AOT for small Pd-NPs. Negligible generation of ammonium for Pd-AOT NPs. Interaction between Pd NPs and AOT is a tool to control catalytic selectivity.