Leveraging molecular metal-support interactions for H2 and N2 activation
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- 作者：Ryan C. Cammarota ; camma031@umn.edu ; Laura J. Clouston ; Connie C. Lu ; clu@umn.edu
- 关键词：Metal-metal bonding ; Bimetallic ; Lewis acid ; Dihydrogen ; Dinitrogen
- 刊名：Coordination Chemistry Reviews
- 出版年：2017
- 出版时间：1 March 2017
- 年：2017
- 卷：334
- 期：Complete
- 页码：100-111
- 全文大小：1978 K
- 卷排序：334
文摘
The catalytic activity of a single metal can be enhanced by a supporting metal. Supporting metals were varied across the first-row period and down Group 13. Metal-support bonding perturbs the metal’s electronic structure and ligand binding. Group 13 supports induce H2 binding at Ni and act cooperatively to cleave H2. Transition-metal supports promote N2 binding and catalytic N2 silylation at Co.