Formation of carbon-rich layer on the surface of SiC fiber by sintering under vacuum for superior mechanical and thermal properties
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文摘
SiC fibers have been intensively developed for application in advanced aerojet engines, stationary gas turbines and nuclear reactors of the future. In this work, SiC fibers with controllable carbon-rich layer were prepared by sintering under vacuum, which could be attributed to the release of gaseous silicon under vacuum at high temperature. The thickness of the carbon-rich layer on the fiber surface could be adjusted by changing the sintering temperature. Moreover, the carbon-rich layer was well distributed on the fiber surface, combining closely with the interior of the fiber. The as-prepared SiC fibers had high tensile strength and relatively low elastic modulus, which was favorable for weaving into different fabrics. Furthermore, the fibers also exhibited excellent ultra-high temperature resistance due to the presence of carbon-rich layer on the surface, which was better than that of the Hi-Nicalon and Hi-Nicalon S fibers.

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