Soya derived heteroatom doped carbon as a promising platform for oxygen reduction, supercapacitor and CO₂ capture

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• 作者：Moumita Rana^a ; K. Subramani^b ; M. Sathish^b ; ^{marappan.sathish@gmail.com} ; Ujjal K. Gautam^a ; ^{ujjalgautam@gmail.com}
• 关键词：Cathode material ; CO2 capture ; Doped carbon ; Supercapacitor ; Oxygen reduction reaction
• 刊名：Carbon
• 出版年：2017
• 出版时间：April 2017
• 年：2017
• 卷：114
• 期：Complete
• 页码：679-689
• 全文大小：2066 K
• 卷排序：114

文摘

Doped carbon allotropes are promising materials for use in a range of applications in energy harvesting and gas adsorption. Synthesis of multifunctional C is however challenging as it requires simultaneous control over surface area, conductivity, chemical nature and loading of heteroatoms in the carbon matrix, usually yielding a material at a time that favours a single application. Pyridinic-N on C-surface, for instance, facilitates oxygen reduction (ORR) and CO2 capture, whereas more heteroatom enhances capacitance. Here we report on soya derived N-doped carbon having high surface area of 1072 m2/g and exhibiting superior performance for all these applications. Supercapacitors made of this material is operable in a wide potential window and possesses specific energy density of 24.3 Wh/kg with 93% capacitive retention beyond 10,000 charge-discharge cycles at a high 10 A/g discharge rate. It also exhibits one of the best performances among bio-derived materials towards ORR with half wave potential of −0.211 V (vs. SCE) in alkaline solution that involve facile multi-electron transfer at rate determining step. Further at 1 bar pressure, it captures an appreciable 14 wt% CO2 at 25 °C and 57.7 wt% at −78 °C.