Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones
详细信息 查看全文
- 作者：Carmen A. Montoyaa ; Clara F. Gó ; meza ; Ana B. Paninhoa ; Ana V.M. Nunesa ; ana.nunes@fct.unl.pt" class="auth_mail" title="E-mail the corresponding author ; Kamran T. Mahmudovb ; c ; kamran_chem@yahoo.com" class="auth_mail" title="E-mail the corresponding author ; kamran_chem@mail.ru" class="auth_mail" title="E-mail the corresponding author ; Vesna Najdanovic-Visakd ; Luí ; sa M.D.R.S. Martinse ; M. Fá ; tima C. Guedes da Silvab ; Armando J.L. Pombeirob ; Manuel Nunes da Pontea
- 关键词：Carbon dioxide ; Epoxide ; Styrene carbonate ; Cyclic carbonates ; Zinc ; Arylhydrazone of B-diketones
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：335
- 期：Complete
- 页码：135-140
- 全文大小：1036 K
文摘
- •
Zinc(II) complexes of arylhydrazones of β-diketones were used for the first time as catalysts in the coupling reaction between CO2 and epoxides.
- •
The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
- •
Catalyst showed promising reactivities and very high selectivities toward the production of cyclic carbonates.