A room temperature synthesizable and environmental friendly heterogeneous ZIF-67 catalyst for the solvent less and co-catalyst free synthesis of cyclic carbonates
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- 作者：Roshith Roshan Kuruppathparambila ; Tharun Josea ; Robin Babua ; Gyu-Young Hwanga ; Amal Cherian Kathalikkattila ; Dong-Woo Kimb ; Dae-Won Parka ; dwpark@pusan.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：CO2 conversion ; Cyclic carbonates ; Heterogeneous ZIF-67 catalyst ; Environmental friendly ; Reusable
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：182
- 期：Complete
- 页码：562-569
- 全文大小：1627 K
文摘
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First report of a Co based ZIF (ZIF-67) catalyst for the chemical fixation of CO2.
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ZIF-67 yields cyclic carbonates at solvent free and co-catalyst free conditions.
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The whole process did not use any kind of organic solvents or hazardous halide ions.
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ZIF-67 was synthesizable in water at room temperature and exhibits high reusability.
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Defects on ZIF-67 external surface supposedly played the key role in catalysis.