Covalent grafting of cobalt carbonyl cluster on functionalized mesoporous SBA- 15 molecular sieve and its applications towards hydroformylation of 1-octene
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- 作者：Maqsood Ahmeda ; Ayyamperumal Sakthivela ; b ; asakthivel@chemistry.du.ac.in" class="auth_mail" title="E-mail the corresponding author ; sakthivelcuk@cukerala.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cobalt carbonyl cluster ; Organosilane grafting ; Hydroformylation ; Heterogenization
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：1 December 2016
- 年：2016
- 卷：424
- 期：Complete
- 页码：85-90
- 全文大小：930 K
文摘
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Cobalt carbonyl cluster was covalently grafted on the surface of SBA-15.
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Organosilane linker (2-propynylcarbonate)-propyl]triethoxysilane used for grafting.
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Covalent grafting evident from FT-IR and solid state NMR studies.
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Resultant Materials showed promising activity for hydroformylation of 1-octene.