An unexpected rearrangement of carbon vertexes in the tricarbollide series. Asymmetrical 7-aryl-nido-7,8,9-C3B8H11 derivatives
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- 作者：Mario Bakardjieva ; Josef Holuba ; Drahomí ; r Hnyka ; Bohumil &Scaron ; tí ; bra ; stibr@iic.cas.cz" class="auth_mail" title="E-mail the corresponding author ; Zdeňka Růžičková ; b ; Ale&scaron ; Růžičkab
- 关键词：Boron hydrides ; Carboranes ; Tricarbaboranes ; Tricarbollides ; NMR spectroscopy ; Reaction mechanisms
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：805
- 期：Complete
- 页码：117-121
- 全文大小：692 K
文摘
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A new mode of cage rearrangement in the tricarbollide series.
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Reactions leading to carboranes of the asymmetrically substituted 7-R-nido-7,8,9-C3B8H11 series.
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Additional mechanistic aspects of rearrangement in the 11-vertex nido tricarbaborane cage.