Kinetic and mechanistic study of bimetallic Pt-Pd/Al2O3 catalysts for CO and C3H6 oxidation
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- 作者：Melanie J. Hazletta ; Melanie Moses-Debuskb ; James E. Parks IIb ; Lawrence F. Allardc ; William S. Eplinga ; wsepling@uh.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Oxidation catalyst ; CO oxidation ; Propylene oxidation ; Bimetallic Pt ; Pd catalysts
- 刊名：Applied Catalysis B: Environmental
- 出版年：2017
- 出版时间：March 2017
- 年：2017
- 卷：202
- 期：Complete
- 页码：404-417
- 全文大小：1967 K
文摘
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CO and C3H6 co-oxidation was characterized.
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CO inhibits Pt and Pt-rich catalysts more strongly than Pd or Pd-rich.
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Carbonates as an intermediate in CO oxidation inhibited CO oxidation.
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C3H6 partial oxidation intermediates caused further inhibition.