Weakly distorted 8-quinolinolato iron(III) complexes as effective catalysts for oxygenation of organic compounds by hydrogen peroxide
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- 作者：Yongjun Wanga ; b ; Xu Wena ; Chunying Ronga ; Senpei Tanga ; Wenfeng Wua ; Chao Zhanga ; Yachun Liua ; yacl315@163.com" class="auth_mail" title="E-mail the corresponding author ; yacl315@hunnu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Zaihui Fua ; fzhhnnu@126.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Heteroleptic 8-quinolinolato iron (III) complexes ; Distorted effect ; Catalytic oxygenation ; Hydrogen peroxide ; Organic compounds
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：411
- 期：Complete
- 页码：103-109
- 全文大小：882 K
文摘
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Two heteroleptic 8-quinolinolato iron(III) complexes were synthesized.
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The heteroleptic complexes showed a superiority for the catalyzed-oxygenation of hydrocarbons.
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This predominance was due to a structural distortion effect of both.
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A free radical mechanism for the catalytic system was proposed.