Anion photoelectron spectroscopy and CCSD(T) calculations of the Cl−⋯N2 complex
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- 作者：Peter D. Watsona ; Hai-wang Yongb ; Kim M.L. Laperea ; Marcus Kettnera ; Allan J. McKinleya ; Duncan A. Wilda ; duncan.wild@uwa.edu.au" class="auth_mail" title="E-mail the corresponding author
- 关键词：Spectroscopy ; Gas phase anions ; Photoelectron ; Mass spectrometry
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：16 June 2016
- 年：2016
- 卷：654
- 期：Complete
- 页码：119-124
- 全文大小：455 K
文摘
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Gas phase anion photoelectron spectrum of the chloride–nitrogen complex is presented.
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CCSD(T) calculations determine geometries of both the anion and neutral complexes.
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Electron detachment energies agree well between experiment and calculations.
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Stability of halide–nitrogen complexes are shown to follow periodic trends.