The Florisil® Catalyzed [1,3]-Sigmatropic Shift of Allyl Phenyl Ethers - An Entryway Into Novel Mycophenolic Acid Analogues

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• 作者：Talamá ; s ; Francisco X. ; Smith ; David B. ; Cervantes ; Alicia ; Franco ; Fidencio ; Cutler ; Serena T. ; et. al.
• 刊名：Tetrahedron Letters
• 出版年：1997
• 出版时间：July 7, 1997
• 年：1997
• 卷：38
• 期：27
• 页码：4725-4728
• 全文大小：160 K

文摘

Florisil® was found to be effective in promoting the [1,3]-sigmatropic shift of mycophenolic acid related allyl phenyl ethers. Several novel mycophenolic acid analogues were thus prepared. Through a crossover experiment using two deuterated analogues of the model system, the reaction was shown to be intramolecular.