β-Boration of α,β-unsaturated carbonyl compounds in ethanol and methanol catalyzed by CCC-NHC pincer Rh complexes
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- 作者：Sean W. Reilly ; Gopalakrishna Akurathi ; Hannah K. Box ; Henry U. Valle ; T. Keith Hollis ; khollis@chemistry.msstate.edu" class="auth_mail" title="E-mail the corresponding author ; Charles Edwin Webster
- 关键词：Enones ; Michael addition ; N-Heterocyclic carbenes ; Pincer ligands ; Rhodium
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 January 2016
- 年：2016
- 卷：802
- 期：Complete
- 页码：32-38
- 全文大小：1025 K
文摘
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A pincer complex catalyzed 1-4-addition reactions at room temperature.
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Cyclic and acyclic enone substrates were reactive under optimized conditions.
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Eco-friendly solvents were applicable with air- and water-stable CCC-NHC pincer Rh complexes.