A recoverable sandwich phosphorotungstate stabilized palladium (0) catalyst for aerobic oxidation of alcohols in water
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- 作者：Lijuan Chena ; b ; ljchen11@163.com" class="auth_mail" title="E-mail the corresponding author ; Tao Fengc ; Pengfei Wangc ; Ziwen Chena ; Riqing Yana ; Bo Liaoa ; b ; Yujun Xianga
- 关键词：Mesoporous aluminophosphate ; Polyoxometalates ; Alcohol oxidation ; Palladium nanoparticle
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：5 August 2016
- 年：2016
- 卷：523
- 期：Complete
- 页码：304-311
- 全文大小：2108 K
文摘
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Pd NPs were stabilized by POMs and in situ encapsulated in mesoporous support.
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Pd NPs remained high dispersion on mesoporous aluminophosphate without aggregation.
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The catalyst is highly efficient for aerobic oxidation of alcohols in water.
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The catalyst could be used for twelve times without obvious loss in activity.