Supporting ligand-assisted N-heterocyclic carbene palladium complexes: characterization, computation, and catalytic activity in Suzuki-Miyaura cross coupling between aryl and heteroaromatic chlorides and various boronic acids
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- 作者：An Shena ; b ; Yu-Cai Hua ; b ; Ting-Ting Liua ; Chen Nia ; b ; Yong Luoa ; b ; Yu-Cai Caoa ; b ; caoyc@srici.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：N-Heterocyclic carbene ; Suzuki&ndash ; Miyaura coupling ; Aryl chlorides ; Heteroaromatic chlorides ; DFT computation
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：11 May 2016
- 年：2016
- 卷：57
- 期：19
- 页码：2055-2058
- 全文大小：2182 K
文摘
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A new series of imine–Pd–(N-heterocyclic carbene) complexes have been developed as efficient catalysts.
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The mechanism has been illustrated though DFT computations, based on the function of supporting ligands.
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Aryl and heteroaromatic chlorides could be synthesized efficiently by using the new catalysts.