The reduction behavior of free chlorine at boron-doped diamond electrodes
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- 作者：Takeshi Watanabea ; Kazumi Akaia ; Yasuaki Einagaa ; b ; einaga@chem.keio.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Boron-doped diamond ; Free chlorine ; Electrochemical sensor ; Oxygen reduction reaction
- 刊名：Electrochemistry Communications
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：70
- 期：Complete
- 页码：18-22
- 全文大小：830 K
文摘
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Observation of the first reduction stage of HClO at a BDD electrode
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The observation of a one-electron reduction is peculiar to BDD.
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Characteristic as nonactive electrode allows to observe of one-electron reduction.
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ClO− is considered as product of one-electron reduction of two HClO.
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ClO− reduction proceeds through ORR by chemical reaction with H2O2.