Thin films of transition metal-containing molecule-based materials: A highlight on electrochemically processed systems
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- 作者：Lydie Valade ; Dominique de Caro ; Mario Basso-Bert ; Isabelle Malfant ; Christophe Faulmann ; Bé ; né ; dicte Garreau de Bonneval and Jean-Pierre Legros
- 关键词：Transition metal ; Molecule-based material ; Electrodeposition ; Thin film ; Silicon
- 刊名：Coordination Chemistry Reviews
- 出版年：2005
- 出版时间：2005
- 年：2005
- 卷：249
- 期：17-18
- 页码：1986-1996
- 全文大小：618 K
文摘
Molecule-based materials show a large variety of physical properties such as conductivity, magnetism, optics, which render them attractive for a new generation of electronic devices. Electrochemical processing is one of the methods that may be applied to grow thin conductive films. Depending on the systems, the technique itself and the two-dimensional growth may afford new phases and/or similar or different properties from those observed on single crystals. Several examples of compounds carrying dithiolato-, polyoxo- or cyano-ligands are provided and the particular use of silicon wafers as substrates is considered.