Characteristics of Cast Stone cementitious waste form for immobilization of secondary wastes from vitrification process

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• 作者：Chul-Woo Chung ; ^{Chul-Woo.Chung@pnnl.gov} ; Wooyong Um ; Michelle M. Valenta ; S.K. Sundaram¹ ; Jaehun Chun ; Kent E. Parker ; Marcia L. Kimura ; Joseph H. Westsik Jr
• 刊名：Journal of Nuclear Materials
• 出版年：2012
• 出版时间：January 2012
• 年：2012
• 卷：420
• 期：1-3
• 页码：164-174
• 全文大小：1439 K

文摘

The high-temperature in vitrification process of radioactive wastes could cause radioactive technetium (⁹⁹Tc) in secondary liquid wastes to become volatile. Solidified cementitious waste forms at low temperature were developed to immobilize radioactive secondary waste. This research focuses on the characterization of a cementitious waste form called Cast Stone. Properties including compressive strength, surface area, phase composition, and technetium leaching were measured. The results indicate that technetium diffusivity is affected by simulant type. Additionally, ettringite and AFm (Al₂O₃-Fe₂O₃-mono) main crystalline phases were formed during hydration. The Cast Stone waste form passed the qualification requirements for a secondary waste form, which are compressive strength of 3.45 MPa and technetium diffusivity of 10^? cm²/s. Cast Stone was found to be a good candidate for immobilizing secondary waste streams.