The crystallographic texture, phase composition and evolution, and nanohardness of a Ti–45Al–2Cr–5Nb alloy processed by selective laser melting (SLM) at various substrate preheating temperatures were investigated. The α2 phase decreases whereas the γ and B2 phases increase with increasing preheating temperature, and the relationship in orientation between B2, α2 and γ phases is described as follows: lineImage" height="22" width="164" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S1359646216300665-si1.gif">. The SLM-processed TiAl alloy shows much higher nanohardness than its traditional casting counterpart, which increases with the increase of preheating temperature. The findings would be a valuable reference for fabricating TiAl components with acceptable texture, phase compositions and nanohardness by SLM.