Efficient π-stacking with benzene provides 2D assembly of trans-[PtCl2(p-CF3C6H4CN)2]
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- 作者：Daniil M. Ivanov ; Yulia V. Kirina ; Alexander S. Novikov ; Galina L. Starova ; Vadim Yu. Kukushkin ; kukushkin@vk2100.spb.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：π-stacking ; Platinum(II) ; p-triflouromethylbenzonitrile ; X-ray structure ; DFT calculations
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 January 2016
- 年：2016
- 卷：1104
- 期：Complete
- 页码：19-23
- 全文大小：927 K
文摘
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New platinum(II) complex trans-[PtCl2(p-CF3C6H4CN)2] was obtained.
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Platinum(II) complex trans-[PtCl2(p-CF3C6H4CN)2] co-crystallizes with benzene.
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Extended π–π interactions were observed by X-ray crystallography.
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Nature of intermolecular π–π interactions was studied by DFT calculations.
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Energy for π–π interactions does not exceed 1.1 kcal/mol.