Photoelectrochemical sensor for pentachlorophenol on microfluidic paper-based analytical device based on the molecular imprinting technique

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• 作者：Guoqiang Sun^a ; Panpan Wang^a ; Shenguang Ge^b ; Lei Ge^a ; Jinghua Yu^a ; Mei Yan^a ; ^{chm_yanm@ujn.edu.cn" class="auth_mail} ; ^{chm_yanm@126.com" class="auth_mail}
• 关键词：Microfluidic paper-based analytical device ; Photoelectrochemical ; Molecular imprinting technique ; Pentachlorophenol
• 刊名：Biosensors and Bioelectronics
• 出版年：15 June, 2014
• 年：2014
• 卷：56
• 期：Complete
• 页码：97-103
• 全文大小：1722 K

文摘

Combining microfluidic paper-based analytical device (渭-PAD) and the molecular imprinting technique, a visible light photoelectrochemical (PEC) sensing platform for the detection of pentachlorophenol (PCP) was established on gold nanoparticles (AuNPs) decorated paper working electrode using polypyrrole-functionalized ZnO nanoparticles. Ascorbic acid (AA) was exploited as an efficient and nontoxic electron donor for scavenging photogenerated holes under mild solution medium and facilitating the generation of stable photocurrent. The microfluidic molecular imprinted polymer-based PEC analytical origami device is developed for the detection of PCP in the linear range from 0.01 ng mL^鈭? to 100 ng mL^鈭? with a low detection limit of 4 pg mL^鈭?. This disposable microfluidic PEC origami device would provide a new platform for sensitive, specific, and multiplex assay in public health, environmental monitoring, and the developing world.