An equiatomic alloy of CuNiSiTiZr is produced by melting and casting.
Electrospark computer numerical control deposition process (ES-CNCD) is proposed.
A high-entropy alloy coating is obtained on TC11 via ES-CNCD.
The thermodynamics of the coating is analyzed by proposing mixing enthalpy matrix.
The coating is identified as BCC coating with micro/nanocrystallines.