Tellurium in organic synthesis: a new approach to trisubstituted γ-butyrolactones with trans–trans relative stereochemistry. Total enantioselective synthesis of (−)-Blastmycinolactol, (+)-Blastmycinone, (−)-NFX-2, and (+)-Antimy

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• 作者：Renan S. Ferrarini ; Alcindo A. Dos Santos ; Joã ; o V. Comasseto
• 关键词：Te/Li exchange reaction ; γ ; -Butyrolactones ; (+)-Blastmycinone ; (+)-Antimycinone ; (− ; )-Blastmycinolactol ; (− ; )-NFX-2
• 刊名：Tetrahedron Letters
• 出版年：2010
• 出版时间：29 December 2010
• 年：2010
• 卷：51
• 期：52
• 页码：6843-6846
• 全文大小：584 K

文摘

The total synthesis of (−)-Blastmycinolactol, (+)-Blastmycinone, (−)-NFX-2, and (+)-Antimycinone was accomplished in few steps in high yields and ee, starting from enantiomerically enriched (S)-Z-vinylic hydroxytellurides.