POBOP pincer complexes of nickel(II): Synthesis and BH activation of the carborane ligand upon oxidation with iodine

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• 作者：Bennett J. Eleazer ; Mark D. Smith ; Dmitry V. Peryshkov ; ^{peryshkov@sc.edu}
• 关键词：Carboranes ; Pincer complexes ; Nickel
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：829
• 期：Complete
• 页码：42-47
• 全文大小：746 K
• 卷排序：829

文摘

B-carboranyl pincer complex of nickel(II) with a strained exohedral BNi bond was synthesized. Oxidation of the complex with iodine resulted in the selective nickel-mediated iodination of the vicinal BH bond. Further iodination of the complex with a large excess of iodine led to iodination of the second boron vertex of the cluster.