High-valent metal-oxo complexes generated in catalytic oxidation reactions using water as an oxygen source

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• 作者：Shunichi Fukuzumi^a ; ^b ; ^{fukuzumi@chem.eng.osaka-u.ac.jp} ; Takahiko Kojima^c ; ^{kojima@chem.tsukuba.ac.jp} ; Yong-Min Lee^a ; Wonwoo Nam^a ; ^{wwnam@ewha.ac.kr}
• 关键词：High-valent metal-oxo complexes ; Redox catalysis ; Electron transfer ; Photocatalyst ; Photoinduced electron transfer
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：333
• 期：Complete
• 页码：44-56
• 全文大小：2296 K
• 卷排序：333

文摘

Generation of metal-oxo complexes by proton-coupled electron transfer. Catalytic oxygenation of substrates by metal complexes using water as an oxygen source. Catalytic water oxidation by one-electron oxidants with metal complexes. Photocatalytic oxidation of water and substrates with metal complexes.