Coordination complexes of copper(II) with herbicide-trichlorophenoxyacetate: Syntheses, characterization, single crystal X-ray structure and packing analyses of monomeric [Cu(γ-pic)3(2,4,5-trichlorophenoxyacetate)]·H2O, [trans-Cu(en)2(2,4,5-trichlorophenoxyacetate)2]·2H2O and dimeric [Cu2<
文摘
Three novel hybrid copper(II) 2,4,5-trichlorophenoxyacetate complexes were synthesized. Crystal lattice is stabilized by array of non-covalent interactions. All complexes show similar mode of carboxylate coordination (monodentate). Variety of structural frameworks in presence of different ligands. Complex 2 shows dual nature (ionic in solution state and covalent in solid state).