Two-dimensional Cu(II)/Cd(II) complexes with double bridged [(μ-EO-N3)(μ-N-N-tetrazolate)] chains: Crystal structures, magnetic behavior and luminescence properties
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- 作者：Min Chenga ; cmcl889917@stu.xjtu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; You-Song Dingb ; 1 ; ding.you.song@stu.xjtu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Zhicheng Zhanga ; zhichengzhang@mail.xjtu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Qin-Xiang Jiaa ; qinxiangjia1984@mail.xjtu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Copper(II) ; Cadmium(II) ; Two-dimensional layers ; Double azide&ndash ; tetrazolate bridges ; Antiferromagnetic couplings ; Luminescence
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 August 2016
- 年：2016
- 卷：450
- 期：Complete
- 页码：1-7
- 全文大小：1869 K
文摘
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Two Cu(II)/Cd(II) compounds with (μ-EO-N3)(μ-N-N-tetrazolate) bridges, have been synthesized.
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The magnetic properties of Cu(II) compound were studied.
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The mixed double bridges transmit antiferromagnetic couplings between Cu(II) ions.
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The emission spectrum of the Cd(II) complex were studied.
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An blue-shift was observed in Cd(II) complex compared with the emission of the free ligand.