Efficient oxidation of ethyl benzene using in situ generated molybdenum acetylide oxo-peroxo complex as recyclable catalyst

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• 作者：Sonali B. Khomane^a ; Dhananjay S. Doke^a ; ^b ; M.K. Dongare^a ; ^c ; S.B. Halligudi^d ; S.B. Umbarkar^a ; ^b ; ^{sb.umbarkar@ncl.res.in} ; ^{shubhangibuin@yahoo.com}
• 关键词：Homogeneous catalysis ; Molybdenum acetylide complex ; Alkyl aromatics ; Carbonyl compounds ; Oxo-peroxo species
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：531
• 期：Complete
• 页码：45-51
• 全文大小：819 K
• 卷排序：531

文摘

Molybdenum acetylide complex as efficient catalyst for ethyl benzene oxidation. In situ formation of molybdenum oxo-peroxo complex in presence of oxidant. Oxidation under mild reaction conditions. Very easy and efficient recycle of catalytically active species. Very high selectivity for carbonyl compound.