Eu³⁺ substitutional defects and their effect on the luminescence spectral and decay dynamics of sal-type one dimensional rare earth coordination polymers and trinuclear complexes

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• 作者：Marvadeen A. Singh-Wilmot^a ; ^{marvadeen.singhwilmot@uwimona.edu.jm} ; Rochette A. Sinclair^a ; Ishenkumba A. Kahwa^a ; Alan J. Lough^b
• 关键词：Coordination polymers ; Exo-coordination ; Lanthanide luminescence ; Red luminophores ; Defect sites ; Decay dynamics
• 刊名：Journal of Luminescence
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：182
• 期：Complete
• 页码：98-106
• 全文大小：1680 K
• 卷排序：182

文摘

Sal-type ligands form compounds with various dimensionalities. Compounds are intense red luminophores. Luminescence and decay dynamics show significant presence of crystal defect sites. The origin and impact of crystal defects can be manipulated in crystal engineering.