Ring-opening polymerization of l-lactide and ε-caprolactone catalyzed by versatile tri-zinc complex: Synthesis of biodegradable polyester with gradient sequence structure
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- 作者：Limiao Lin ; Yonghang Xu ; Shuanjin Wang ; Min Xiao ; stsxm@mail.sysu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Yuezhong Meng ; mengyzh@mail.sysu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Schiff base tri-zinc complexes ; l-Lactide ; ε-Caprolactone ; Gradient ; Copolymerization
- 刊名：European Polymer Journal
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：74
- 期：Complete
- 页码：109-119
- 全文大小：1066 K
文摘
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A gradient poly(lactide-grad-caprolactone) was synthesized at first time.
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Both copolymer composition and structure have great impacts on their properties.
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This method can be used to synthesize biodegradable aliphatic polyester with a diverse range of properties.