Intercalation of thiacalix[4]arene anion via calcined/restored reaction into LDH and efficient heavy metal capture
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TCAS–LDH composites with different TCAS arrangement were synthesized via calcined–restored method.

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The obtained composites are highly selective and efficient for Pb2 + and Cu2 +.

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Adsorption of Pb2 + and Cu2 + is probably due to the bridging S atoms.

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The adsorption kinetics and isotherm were discussed.

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