Effect of temperature on gasification performance and sodium transformation of Zhundong coal
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A high sodium Zhundong coal was gasified in a novel design of fluidized bed gasifier.

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Zhundong coal shows good gasification performance due to the catalytic effect of sodium in coal ash.

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The experimental results are in accordance with the ternary phase diagram prediction of Na2O-SiO2-Al2O3.

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Ways of inhibiting agglomeration are proposed for high sodium coal gasification.

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The formation of high melting point sodium-containing compound NaAlSiO4 is the essence to inhibit agglomeration.

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