Size-dependent magnetic and electrocatalytic properties of nickel phosphide nanoparticles
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Ni2P nanoparticles (NPs) with different sizes were synthesized via thermal decomposition of single-source precursor.

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The size of Ni2P NPs can easily be controlled by changing reaction temperature.

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The smaller Ni2P NPs exhibit superparamagnetism and the larger Ni2P NPs exhibit ferromagnetic characteristic at 300 K.

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The Ni2P NPs with small size exhibit higher electrocatalytic activity for the HER.

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The magnetic and electrocatalytic properties of the Ni2P NPs are size-dependent.

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