The Pd/Pd2+ co-modified (BiO)2CO3 microspheres were fabricated hydrothermally.
Pd/Pd2+ co-modified (BiO)2CO3 exhibited highly enhanced visible photocatalysis.
The doped Pd2+ could elevate the valence band and narrow band gap.
The Pd metal deposition could improve the charge separation and transfer.
The increased visible absorption and enhanced charge separation were achieved.